However, in order for an electronic assembly to be considered as truly leadfree, every step of the assembly process must utilize leadfree materials including smt reflow, th soldering, rework, field repair and eol recycling infrastructure. The program taps the research capabilities of the university of massachusetts to advance the investigation, development and evaluation of sustainable. Soldering will include information on acceptable and defective lead free solder joints. Nonwetting insufficient solder dewetting icicling cold solder joints. This presentation is only a summary rohs globally latest update materials components and boards solders leadfree choices leadfree smt process preventing defects in smt lf wave soldering process preventing defects in wave assembly lf hand soldering and rework the information contained in this presentation is accurate as per the industry information available. Development of a lead free solder bumped rfic switch process. Leadfree wave soldering global leader in solder and solder. Being an uptodate book on this changing field, it is an essential. Peter biocca, senior development engineer, kester, des plaines, illinois. This booklet is intended to guide the future users of leadfree solders to the most appropriate leadfree alloys and processes for their applications. The nasadod lead free electronics project confirmed that pad cratering is one of the dominant failure modes that occur in various board level reliability tests, especially under dynamic loading harsh environments. Development of lead free vehicle products denso ten. Solder joint failures in automotive electronics would not be different than the failures in other types of electronics.
Developing a reliable lead free smt assembly process author. For a static solder pot, we designed the pot, which deteriorates faster when using lead. Developing and analyzing leadfree soldering processes for. An alloy that is used as a leadfree solder consisting of tin and copper considered to be applicable for wave or re. It is intended as a reference guide to engineers in the industry who are or who will be migrating to lead free soldering. Timely and up to date, this reference covers key topics including legislation, smt, wave, rework, alloys, test, and reliability.
The next section of this paper discusses the motivation behind the development of the repairprocess model. How can a good leadfree hand soldering process be had, which will ease the leadfree soldering operation. We are providing the microelectronics industry with measurement tools and data to address solder issues. So it should come as no surprise that assembling 01005s with lead free solder paste is a great challenge. One of the primary efforts by the electronics industry has involved the development of alternative solders to replace the traditional leadcontaining alloys. To address the information gap on the environmental impacts of leaded and leadfree solders, epas dfe program entered into a voluntary partnership with representatives of the electronics industry and other interested parties to evaluate the environmental impacts of tinlead and leadfree solders.
Leadfree smt can be challenging however, this challenge can be. Selection of alloys the lead free wave solder process is in the early stages of development, it is estimated that currently less than 5% of all wave solder baths are using lead free alloys. Solder paste handling the shelf life and storage conditions of the lead free pastes may be different from the eutectic solder pastes. Flip chip process development and relaibility evaluation with. This paper describes the possibilities to use metallized plastic film capacitors in lead free soldering process. Leadfree solder process development ebook written by gregory henshall, jasbir bath, carol a. With the move to adopt lead free soldering technology, and the consequently higher reflow process temperatures, optimisation of the reflow profile will gain a renewed emphasis, increasing the. Mechanical properties and microstructure investigation of. It is a good resource to demonstrate the many facets of leadfree solder interconnection, and can serve as a very informative technical reference. Leadfree defects in reflow soldering the ipc610d acceptability of electronic assemblies will shortly be available and section 5. Leadfree solder process development isbn 9780470410745. The main concern with leadfree wave soldering is the potential increase in soldering defects.
They also used noclean liquid flux and noclean solder paste. He has more than twenty years experience in materials research and development, including twelve years of experience with soldering alloys and electronics manufacturing and nine years focused on leadfree technology. The motivation for developing leadfree solders is to remove pb from electronic manufacturing and waste disposal processes. It also is necessary to check the suitability of a given lead free solder for jointing. Wayne johnson the characterization of leadfree solders, especially after isothermal aging, is very.
This paper will discuss the wafer level process development of a lead free solder bumped process and necessary process controls and wafer level qualification results. For a flow solder bath, the special treatments given to the areas susceptible to erosion by solder can reduce the frequency of replacement of deteriorated parts. Leadfree solder process development, covers a list of key topics including. Leadfree and lead solder do perform the same function. Fundamentals of leadfree solder interconnect technology. In addition to purely technical concerns, the transition to lead.
Leadfree solder process development by gregory henshall. Download for offline reading, highlight, bookmark or take notes while you read leadfree solder process development. Soldering will include information on acceptable and defective leadfree solder joints. Free solder process development wiley online books. This will allow engineers to make a direct comparison of tin lead and lead free solders and assess the impact on cost and availability over an entire field life for an entire population of systems. The robust method was utilized in the development of a lead free process for manufacturing an automotive smt product. Factors leading to ionic migration in lead free solder hirokazu tanaka ionic migration also known as electrochemical migration is an electrochemical phenomenon related to chemical solutions and electric potential. The following defects can see increases in a poorly optimized lead free wave process. Please obtain the latest information for your process needs since leadfree assembly requirements may change. Soldering of smd film capacitors in practical lead free processes. Selection of alloys the leadfree wave solder process is in the early stages of development, it is estimated that currently less than 5% of all wave solder baths are using leadfree alloys. In the following, the development of a temperature profile for snagcu reflow soldering will be presented which considers the different aspects of serial production, reliability of solder joints and heat impact on the devices. Elastic properties of metallic elements used in electronic packaging. Introduction flip chip bonding is defined as the connection of a device, bond pads face down, onto a substrate with a matching array of bond pads.
Figure 1 comparison of 01005 componen t size with larger size components. Leadfree solder process development isbn 9780470410745 pdf. The issue of tinlead solder versus leadfree solder reliability and whether lead in solders used for circuit board assembly impacts the reliability. He has more than twenty years experience in materials research and development, including twelve years of experience with soldering alloys and electronics manufacturing and nine years focused on lead free technology. Their results indicate that the effects of adopted as an alternative to eutectic tin lead snpb thermal aging on solder joint shear strength are much solder. What are the key process requirements to achieve reliable leadfree smt. Development of a high performance leadfree wave solder.
Peter biocca, senior development engineer, kester, des plaines, illinois telephone 972. It is intended as a reference guide to engineers in the industry who are or who will be migrating to leadfree soldering. Development of a lead pbfree soldering process for. Higher process temperature requirements when compared to conventional lead solders which have a processing temperature of approximately 230c 446f, leadfree alternatives require extended exposure preheating and reflow at higher maximum temperatures. Solder profile for wave soldering process figure 2 classification wave soldering profile for tht components refer to en617601. Many of the electronic companies and manufacturers around the globe were using tinlead snpb solder solder wire, solder bar, solder paste for pcb assembly and rework repairing. Leadfree solders, grain structure, nucleation, solidification introduction most of the significant differences between the commonly used leadfree solders, those based on additions of copper andor silver to tin, and the eutectic tinlead solder that they are replacing can be. The thermal cycling ramifications of leadfree solder on the. The book gives wide perspectives on the technical insights of leadfree solder interconnect system and reliability prediction in industry while adding very valuable industry insights. So it should come as no surprise that assembling 01005s with leadfree solder paste is a great challenge. Below are photographs of two leadfree solder pastes after hot slump testing at.
Activation energy versus strain rate for two leadfree eutectic solders sn3. Investigation of the leadfree solder joint shear performance. Development of leadfree wave soldering process request pdf. Y amamoto et al assembly technology using lead free solder damaging electronic components. The current 2017 version of the inemi roadmap, anticipates a rising trend in the % of low temperature solder used for board assembly, with a projection of 10% in 2021. Pad cratering is a latent defect that may occur during assembly, rework, and post assembly handling and testing.
The most common choices for lead free solders are different tinsilvercopper sac alloys. Transcript phil welcome to board talk with phil zarrow and jim hall of itm consulting, the assembly brothers, pick and place. Emphasizing practical knowledge of lead free soldering rather than theory, lead free solder process development is written by experts who are or who have been heavily involved in lead free implementation at the product level. Apr 21, 2009 lead free soldering materials and processes. Lifecycle assessment for leadfree solder in electronics. They did not bother to clean the pcb and the flux residue after assembly. Processes using sac solders cause extra stress, because of increased process temperatures, especially to the plastic materials. Prerequisites on the basis of automotive electronic control units.
The most obvious difference from the industry standard was the substantially higher melting temperature of 221c versus 183c sn63pb37. Whether leadfree or lead solder, the function is the same. For these reasons, wetting failures for lead free solder such as unmolten solder, nonwetting to components, and head. Coming to you from the itm cave high above mount rialto. Introduction the 2004 inemi roadmap identified a gap in industry information and research relating to lead free wave soldering processes and reliability of these lead free assemblies. Here the mechanical properties of the snagcubi alloys were compared with those of comparable snagcu alloys. Pdf leadfree soldering materials and processes researchgate. Chapter 5 summarizes the studys results and discusses the research findings. The word solder comes from the middle english word soudur, via old french solduree and soulder, from the latin solidare, meaning to make solid.
Shop for leadfree solder, including sn96 and sn99 alloys, available in a variety of diameters and lengths. Our leadfree solder featuries excellent wettability and hard nonconductive residues. In light of this need we planned and executed an experimental protocol to develop an optimized assembly process for 01005. Factors leading to ionic migration in leadfree solder hirokazu tanaka ionic migration also known as electrochemical migration is an electrochemical phenomenon related to chemical solutions and electric potential. Flip chip process development and relaibility evaluation. Lead free solder and composition lead free solder wire. There has been major interest in leadfree soldering within the electronics. To avoid issues related to paste handling, you must strictly. The study involved the development of a flip chip assembly process followed by a reliability evaluation comparing the fatigue resistance of the snagcu alloy to that of eutectic snpb solder. Ieee410745 leadfree solder process development covers a list of key topics including. Characterization of leadfree solders for electronic packaging hongtao ma doctor of philosophy, may 10, 2007 m. Currently, thermal protection is used to maintain the ambient temperature of the electronic. Process development for 01005 leadfree passive assembly.
Development of a high performance leadfree wave solder alloy. There has been vigorous development of alternative solder alloys largely based upon sn. However, different products and applications will use different solder. Lf wave soldering process preventing defects in wave assembly lf hand soldering and rework the information contained in this presentation is accurate as per the industry information available at the time of this revision. Development of a lead free solder bumped rfic switch. Leadfree solder process development covers general leadfree soldering topics written by those specializing in these areas.
Solder paste handling the shelf life and storage conditions of the leadfree pastes may be different from the eutectic solder pastes. The primary challenge in this transition is adapting to the higher temperatures that are required in the leadfree soldering process. For these reasons, wetting failures for leadfree solder such as unmolten solder, nonwetting to components, and head. Reliability issues of leadfree solder joints in electronic. The thermal cycling ramifications of leadfree solder on. Lee, in reference module in materials science and materials engineering, 2017. Discusses the growth mechanisms of tin whiskers and the effective mitigation strategies necessary to reduce whisker growth risks this book covers key tin whisker topics, ranging from fundamental science to practical mitigation strategies. Pb solder use dates back to 3800 bc when it was used to produce ornaments and jewelry harmful effects of excess pb on the human body are well documented pb gets into the body only through inhalation or ingestion acts as a neurotoxin, inhibits hemoglobin production, effects brain development children are more susceptible than adults. These results will provide the baseline information for the future study in lead free solder materials. However, the purpose of this exercise is to develop an assembly process while trying to understand the impact of two process parameters. The main concerns for the cost of leadfree solder development include the cost of solder materials e. Solder and solderability are increasingly tenuous links in microelectronics assembly as a consequence of ever shrinking chip and package dimensions, and the movement toward environmentally friendly leadfree solders. The main concern with lead free wave soldering is the potential increase in soldering defects.
The development of a qualification temperature profile for. It provides updates in areas where research is ongoing and addresses various topics that are. With the move to adopt leadfree soldering technology, and the consequently higher reflow process temperatures, optimisation of the reflow profile will gain a. Soldering of smd film capacitors in practical lead free. When leadfree solders were first introduced to the electronics industry in the early 1990s, the tinsilver alloy composed of sn96. Nonwetting insufficient solder dewetting icicling cold solder joints grainy joints blow holes solder balls fillet lifting. Developing a reliable leadfree smt assembly process kester. The reaction mechanisms of ionic migration can be classified into three processes. This booklet is intended to guide the future users of lead free solders to the most appropriate lead free alloys and processes for their applications. Grain refinement for improved leadfree solder joint. Lead free defects in reflow soldering the ipc610d acceptability of electronic assemblies will shortly be available and section 5. The following defects can see increases in a poorly optimized leadfree wave process.
Lead free smt can be challenging however, this challenge can be reduced if the. Pdf evaluation of reflow ovens for leadfree soldering. Impacted the most by this requirement are the thermoplastic materials in connectors and board level components such as. Material properties of a viainpad chipscale package printed circuit board. Leadfree soldering of surface mount technology smt has been studied. The flux core in the wire and leadfree fluxes contain harsh reducing agents that are highly irritatating to wet membranes like the sinuses and the eyes the flux used in leadfree soldering has a shelf life. Leadfree wave soldering global leader in solder and. The design of experiment doe is actually the first phase of a solder joint relia bility evaluation that studies thermal fatigue 1. As an industryled consortium, part of inemis mission is to identify future. Lead free, pb free, wave soldering, process, solder, alloy, flux. Investigation and development of tinlead and leadfree.
The main concerns for the cost of lead free solder development include the cost of solder materials e. Many electronics use solder as the glue to attach components to circuit boards. The thermal cycling ramifications of leadfree solder on the electronic assembly repair process andrew chaloupka, peter sandborn, and anthony konoza. However, in order for an electronic assembly to be considered as truly lead free, every step of the assembly process must utilize lead free materials including smt reflow, th soldering, rework, field repair and eol recycling infrastructure. Gregory henshall is master engineer at hewlettpackard company in palo alto, california. Lead free solder process development, covers a list of key topics including.
Ma and suhling 2009 inform that the harmful effects of tin lead and lead free solder in bar and paste forms were studied and funded by the us environmental protection agency epa. Factors leading to ionic migration in leadfree solder. In fact, solder must first be melted in order to adhere to and connect the. An alloy that is used as a leadfree solder consisting of tin, silver and copper as the main constituents. Developing a reliable leadfree smt assembly process author. Reviews theories of mechanicallyinduced tin whiskers with case studies using pure tin and other lead free finishes shown to. When manufacturing specific products, they must use leadfree solder. Leadfree assembly development for servers ibm server systems eligible for the eu rohs lead in solder for servers exemption to transition to leadfree solder assembly on a case by case basis although many production card assemblies now include sac bga components, snpb assembly remains lower risk than full pbfree in many cases. Development and validation of leadfree wave soldering process. Testability of lead free printed circuit assemblies. Major factors that can create variation in a lead free process were identified, including lead free solder paste brand, paste print speed, oven reflow temperatures and times, and reflow environment. Request pdf development of leadfree wave soldering process leadfree wave soldering was studied in this work using a 95. In a recent study, which appeared in the leadfree update by tech search international in december 2004, hand soldering was found to be more problematic to implement when compared to leadfree wave soldering and smt.
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